2205 (PREN≈34–36) covers most high-chloride duties; 2507 (PREN≈42–43) offers higher corrosion resistance and strength for seawater and oil & gas.
2205 (S32205/S31803) and 2507 (S32750) are the common duplex stainless steels. Selection depends on how severe the corrosion is and the required strength:
1) For general high-chloride service (cooling water, FGD), 2205 is usually sufficient.
2) For high temperature + high chloride, severe crevices or longer life, choose 2507.
3) 2507 demands tighter welding and forming control, with WPS/PQR and ferrite content control.
4) Do not move to 2507 blindly on cost-sensitive projects; assess measured medium data first.
The key with duplex is the ferrite/austenite balance: cooling rate and heat input after welding affect life more than the grade selection alone.