The five stainless steel families: austenitic, ferritic, martensitic, duplex, PH
Stainless steels fall into five families by microstructure, differing in corrosion, strength, magnetism and welding. Classify first, then choose the grade.
Stainless steels are commonly grouped into five families by room-temperature microstructure — the first step in grade selection:
1) Austenitic (mostly 300 series): 304/316L/321 etc.; good corrosion resistance and formability, non-magnetic (may become slightly magnetic after cold working), weldable, largest volume.
2) Ferritic (400 series): 430/409/439 etc.; magnetic, lower cost, moderate corrosion resistance; used in decoration, appliances and automotive exhaust.
3) Martensitic: 410/420/440C etc.; hardenable by quenching and tempering, lower corrosion resistance; used for cutlery, bearings and valves.
4) Duplex: 2205/2507 etc.; austenite + ferrite, high strength, good chloride and stress-corrosion resistance; used in seawater, chemical and pressure service.
5) Precipitation hardening (PH): 17-4PH/15-5PH etc.; strengthened by aging, tensile strength above 1000 MPa; used in aerospace and precision parts.
Quick guide: corrosion + welding → austenitic; cheap + magnetic → ferritic; hardness → martensitic; high strength + chloride → duplex; high strength + precision → PH.
Note that grades within a family still differ significantly (e.g. 304 vs 316L with molybdenum); the family is only the first filter.
Compiled by SteelWe editors and industry experts. For industry exchange only; not trading or investment advice. Cite the source when quoting.